kijanimicin

CHEBI:220048 chemically defined MAPPED CHEBI EXACT_MATCH

Ontology mapping

Primary identifier
CHEBI:220048
Ontology label
Kijanimicin

Physicochemical roles

Synonyms (1)

SynonymTypeSourceOccurrences
methyl N-[(2R,3R,4S,6R)-6-[[(1S,3R,6S,7E,9S,11E,13S,16S,17S,18S,20S,21R,22S,23E)-17-[(2R,4R,5S,6S)-4-[(2S,6S)-4-[(2S,4S,5R,6S)-4,5-dihydroxy-6-methyloxan-2-yl]oxy-5-[(2R,4R,5R,6S)-4-hydroxy-5-methoxy-6-methyloxan-2-yl]oxy-6-methyloxan-2-yl]oxy-5-hydroxy-6-methyloxan-2-yl]oxy-23-hydroxy-4-(hydroxymethyl)-3,8,12,18,20,22-hexamethyl-25,27-dioxo-26-oxapentacyclo[22.2.1.01,6.013,22.016,21]heptacosa-4,7,11,14,23-pentaen-9-yl]oxy]-2,4-dimethyl-4-nitrooxan-3-yl]carbamate EXACT_SYNONYM chebi_synonym_review

Rejected enrichment labels (1)

Provenance-only candidates: these are not synonyms and do not resolve to this record.

Rejected labelDispositionSourceOccurrences
produces: kijanimicin REJECTED_LABEL sssom_other_backfill

Chemical properties

Molecular formula
C67H100N2O24
Inchi
InChI=1S/C67H100N2O24/c1-29-15-18-45(88-52-27-65(11,69(79)80)60(38(10)87-52)68-64(78)82-14)30(2)20-40-21-39(28-70)33(5)26-67(40)62(76)53(63(77)93-67)61(75)66(12)42(29)17-16-41-54(66)31(3)19-32(4)57(41)91-51-24-46(56(74)35(7)84-51)89-50-25-47(90-48-22-43(71)55(73)34(6)83-48)59(37(9)86-50)92-49-23-44(72)58(81-13)36(8)85-49/h15-17,20-21,31-38,40-52,54-60,70-75H,18-19,22-28H2,1-14H3,(H,68,78)/b29-15+,30-20+,61-53-/t31-,32-,33+,34-,35-,36-,37-,38+,40+,41-,42-,43-,44+,45-,46+,47?,48-,49+,50-,51-,52-,54+,55-,56-,57-,58-,59?,60-,65-,66+,67-/m0/s1
Smiles
COC(=O)N[C@H]1[C@@H](C)O[C@@H](O[C@H]2C/C=C(C)[C@@H]3C=C[C@@H]4[C@@H](O[C@H]5C[C@@H](O[C@H]6CC(O[C@H]7C[C@H](O)[C@@H](O)[C@H](C)O7)C(O[C@@H]7C[C@@H](O)[C@@H](OC)[C@H](C)O7)[C@H](C)O6)[C@@H](O)[C@H](C)O5)[C@@H](C)C[C@H](C)[C@H]4[C@]3(C)/C(O)=C3/C(=O)O[C@]4(C[C@@H](C)C(CO)=C[C@H]4/C=C/2C)C3=O)C[C@]1(C)[N+](=O)[O-]
Data source
CHEBI sqlite (oaklib)

Evidence (1)

LEXICAL_MATCH via kgmicrobe.compound:kijanimicin

Auto-curated from UNMAPPED_PENDING_CURATION queue; OLS exact-label match

Occurrence statistics

Total occurrences
0
Distinct media
0

Curation history

TimestampCuratorActionNew statusChanges
2026-04-19T06:10:55.017713+00:00 audit_propose_chebi_for_unmapped CREATED_FROM_UNMAPPED_QUEUE MAPPED Created new ingredient from kgmicrobe.compound:kijanimicin with auto-curated CHEBI CHEBI:220048 (Kijanimicin)
2026-05-01T07:35:34.216265+00:00 auto_classify_ingredient_type AUTO_CLASSIFY_INGREDIENT_TYPE set ingredient_type=SINGLE_INGREDIENT (CHEBI primary)
2026-05-01T08:08:30.216304+00:00 auto_classify_ingredient_type AUTO_BACKFILL_CHEBI_CHEMISTRY molecular_formula=C67H100N2O24; inchi=InChI=1S/C67H100N2O24/c1-29-15-18-45(88-52-27-65(1; smiles=COC(=O)N[C@H]1[C@@H](C)O[C@@H](O[C@H]2C/C=C(C)[C@@
2026-05-02T03:12:15.320791+00:00 auto_classify_ingredient_type AUTO_CLASSIFY_INGREDIENT_TYPE set ingredient_type=SINGLE_INGREDIENT (chemical structure populated (molecular_formula))
2026-06-02T07:05:13.390311+00:00 infer_roles_from_name_lists ANNOTATED Added media role: SELECTIVE_AGENT (confidence: 0.80)
2026-07-20T00:00:00+00:00 migrate_media_roles_to_facets ANNOTATED Migrated legacy media_roles to role facets (#128): SELECTIVE_AGENT -> physicochemical_roles.SELECTIVE_AGENT
2026-09-02T17:40:44.716277+00:00 claude_sssom_surface_form_backfill ADDED_SYNONYMS Recovered 1 surface form(s) that the published SSSOM `other` carried but no curated record did, so a rebuild would have dropped them from KGX: 'produces: kijanimicin'. Tokens already present on the kg-microbe ontology node were left out as redundant (#520).
2026-09-22T06:14:49.563933+00:00 claude LLM REJECTED_TRAIT_SYNONYMS Retyped activity/assay phrases as provenance-only REJECTED_LABEL because they describe a process or organism trait, not an ingredient name (#703): 'produces: kijanimicin'. Preserved original text and source metadata. No identity, mapping, role, or remaining-synonym claim was adjudicated.