NaH2PO4•H2O

CHEBI:114249 chemically defined REJECTED CHEBI NARROW_MATCH

Ontology mapping

Primary identifier
CHEBI:114249
Ontology label
sodium dihydrogenphosphate monohydrate
Notes
CultureMech placeholder_id: 2; reviewed on 2026-05-11 and left unmapped for hydrate-state curation rather than merging to CHEBI:37585 anhydrous sodium dihydrogenphosphate.

Synonyms (1)

SynonymTypeSourceOccurrences
NaH2PO4•H2O(MCIB 742) RAW_TEXT CultureMech

Evidence (1)

DATABASE_MATCH via Edison LITERATURE deep research

Edison literature research (research/ingredients/NaH2PO4H2O-edison-literature.md) identifies this as sodium dihydrogen phosphate MONOHYDRATE, CAS 10049-21-5. CHEBI:37585 'sodium dihydrogenphosphate' is the ANHYDROUS form (its own dbxref is CAS 7558-80-7), so the two are distinct substances -- MAPPING_SEMANTICS.md Section 3: the hydrate takes its own cas: identifier with a narrowMatch to the anhydrous parent, rather than being folded onto it.

Occurrence statistics

Total occurrences
0
Distinct media
0

Curation history

TimestampCuratorActionNew statusChanges
2026-03-09T06:54:18.022301+00:00 import_from_culturemech IMPORTED UNMAPPED Initial import from CultureMech pipeline
2026-05-11T05:36:00Z mediaingredientmech-agentic-curation LLM REVIEWED_HYDRATE_AMBIGUITY UNMAPPED Reviewed against local CHEBI:37585 mapped records; not merged because the source term is explicit NaH2PO4 monohydrate while the local mapped representatives carry anhydrous sodium dihydrogenphosphate chemistry.
2026-08-06T00:00:00+00:00 promote_resolved_unmapped PROMOTED_TO_MAPPED MAPPED Promoted UNMAPPED_0028 -> cas:10049-21-5 "sodium dihydrogenphosphate" (NARROW_MATCH); mapping_status UNMAPPED -> MAPPED, SSSOM row added.
2026-09-23T04:49:55.744418+00:00 claude LLM MERGED_INTO REJECTED Merged into CHEBI:114249 'Sodium phosphate monobasic monohydrate'; occurrences transferred. Tombstoned REJECTED, SSSOM rows dropped. The cas: identity was the Section 3 step 2 fallback on the premise that ChEBI has no monohydrate term; CHEBI:114249 sodium dihydrogenphosphate monohydrate exists, xrefs cas:10049-21-5, and is held by this record: one substance under two identifiers (#312).
2026-09-23T04:53:11.712894+00:00 claude LLM CORRECTED REJECTED identifier cas:10049-21-5 -> CHEBI:114249 on the merge tombstone, so the merged name is credited to the live record that holds the identifier (Rule K; the #414 Mgcl2x_6_H2o precedent). The 2026-08-06 promotion used the Section 3 step 2 cas: fallback on the premise that ChEBI has no hydrate term. CHEBI:114249 'sodium dihydrogenphosphate monohydrate' (H2O.H2O4P.Na, InChIKey BBMHARZCALWXSL-UHFFFAOYSA-M) exists and xrefs cas:10049-21-5, the very CAS the record was keyed on, and Sodium_phosphate_monobasic_monohydrate already holds it: one substance under two identifiers -> merge (#312).
2026-09-23T05:17:01.921583+00:00 claude LLM CORRECTED REJECTED ontology_id CHEBI:37585 ('sodium dihydrogenphosphate') -> CHEBI:114249 ('sodium dihydrogenphosphate monohydrate') on the merge tombstone, so the merged name is credited to the live record that holds the identifier (Rule K; the #414 Mgcl2x_6_H2o precedent). The 2026-08-06 promotion used the Section 3 step 2 cas: fallback on the premise that ChEBI has no hydrate term. CHEBI:114249 'sodium dihydrogenphosphate monohydrate' (H2O.H2O4P.Na, InChIKey BBMHARZCALWXSL-UHFFFAOYSA-M) exists and xrefs cas:10049-21-5, the very CAS the record was keyed on, and Sodium_phosphate_monobasic_monohydrate already holds it: one substance under two identifiers -> merge (#312).