ambiguine D isonitrile
naturalproductmech:mibig-ed15521036 MINTED SEEDED
Structure
| Standard InChIKey | BEUWKFSFCQGVEY-QJQSJIDVSA-N |
|---|---|
| SMILES | C[C@@]1([C@@H](C[C@H]2[C@@]3([C@@]1([C@@H]4[C@@H](O4)C(C5=NC6=CC=CC(=C6[C@@]53O)C2(C)C)(C)C)[N+]#[C-])O)Cl)C=C |
| Stereochemistry | fully defined |
| Cross-references | pubchem:21610115 |
Filing pathway
Alkaloids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is terpene, other, from MIBiG.
Producer organisms 1
A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.
| Taxon | Basis | Cluster | Evidence |
|---|---|---|---|
| Fischerella ambigua UTEX 1903 NCBITaxon:230521 |
SOURCE_ASSERTION | mibig:BGC0001126 | PMID:24180436 |
Occurrences 4
Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.
| Taxon | Source | Reference |
|---|---|---|
| Fischerella NCBITaxon:1190 |
LOTUS | DOI:10.1021/NP060495R |
| Fischerella NCBITaxon:1190 |
LOTUS | DOI:10.1021/NP060495R.S001 |
| Fischerella ambigua NCBITaxon:56108 |
LOTUS | DOI:10.1021/JO00029A014 |
| Fischerella ambigua NCBITaxon:56108 |
CYANOMETDB | DOI:10.1021/jo00029a014 |
Biosynthetic gene clusters 1
| Accession | Host | Locus evidence | Genome |
|---|---|---|---|
| mibig:BGC0001126 | Fischerella ambigua UTEX 1903 NCBITaxon:230521 |
CLUSTER_DEMONSTRATED | genbank:KF664586.1 |
A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.
Provenance
| Source concept | Source | Version |
|---|---|---|
| BGC0001126 | MIBIG | 4 |
This page is generated from data/natural_products/alkaloids/ambiguine-d-isonitrile.yaml, which is generated from the committed inventories. Neither is edited by hand.