ambiguine H isonitrile
naturalproductmech:mibig-eb25c9b521 MINTED SEEDED
Structure
| Standard InChIKey | DBOXZAYTFKDLHJ-KPQBMEGNSA-N |
|---|---|
| SMILES | [H][C@@]12CC[C@@](C)(C=C)[C@@H]([N+]#[C-])[C@@]1([H])C1=C(NC3=CC=CC(=C13)C2(C)C)C(C)(C)C=C |
| Stereochemistry | fully defined |
| Cross-references | npatlas:NPA018261 |
Filing pathway
Alkaloids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is other, from MIBiG.
Producer organisms 1
A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.
| Taxon | Basis | Cluster | Evidence |
|---|---|---|---|
| Fischerella ambigua UTEX 1903 NCBITaxon:230521 |
SOURCE_ASSERTION | mibig:BGC0001612 | PMID:26629885 |
Occurrences 2
Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.
| Taxon | Source | Reference |
|---|---|---|
| Fischerella NCBITaxon:1190 |
LOTUS | DOI:10.1021/NP060495R |
| Fischerella NCBITaxon:1190 |
LOTUS | DOI:10.1021/NP070346O |
Biosynthetic gene clusters 1
| Accession | Host | Locus evidence | Genome |
|---|---|---|---|
| mibig:BGC0001612 | Fischerella ambigua UTEX 1903 NCBITaxon:230521 |
CLUSTER_UNSTATED | genbank:KX451322.1 |
A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.
Provenance
| Source concept | Source | Version |
|---|---|---|
| BGC0001612 | MIBIG | 3 |
This page is generated from data/natural_products/alkaloids/ambiguine-h-isonitrile.yaml, which is generated from the committed inventories. Neither is edited by hand.