NaturalProductMech

himastatin

CHEBI:190009 EXACT SEEDED antibacterial

A dimeric cyclohexadepsipeptide with formula C72H104N14O20. It is an antibiotic isolated from Streptomyces hygroscopicus and exhibits antitumor and antibacterial activity.

Structure

Standard InChIKeyOZPNLJQULOIOGU-UPABGHPRSA-N
SMILES[H][C@@]12NC3=CC=C(C=C3[C@]1(O)C[C@@H]1N2C(=O)[C@H](NC(=O)[C@H](CC(C)C)NC(=O)[C@H]2C[C@@H](O)CNN2C(=O)[C@@H](OC(=O)[C@H](NC1=O)C(C)C)C(C)C)[C@H](C)O)C1=CC=C2N[C@@]3([H])N4[C@@H](C[C@@]3(O)C2=C1)C(=O)N[C@H](C(C)C)C(=O)O[C@@H](C(C)C)C(=O)N1NC[C@H](O)C[C@@H]1C(=O)N[C@@H](CC(C)C)C(=O)N[C@H]([C@H](C)O)C4=O
Stereochemistryfully defined
Cross-referencesnpatlas:NPA016115

Filing pathway

Amino acids and peptides — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is nrps, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Streptomyces himastatinicus ATCC 53653
NCBITaxon:457427
SOURCE_ASSERTION mibig:BGC0001117 PMID:21726028

Occurrences 4

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Streptomyces hygroscopicus
NCBITaxon:1912
LOTUS DOI:10.7164/ANTIBIOTICS.43.956
Streptomyces hygroscopicus
NCBITaxon:1912
LOTUS DOI:10.7164/ANTIBIOTICS.43.961
Streptomyces hygroscopicus
NCBITaxon:1912
LOTUS DOI:10.7164/ANTIBIOTICS.49.299
Streptomyces himastatinicus ATCC 53653
NCBITaxon:457427
CHEBI PMID:2211363

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0001117 Streptomyces himastatinicus ATCC 53653
NCBITaxon:457427
CLUSTER_UNSTATED genbank:FR823394.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Elsewhere in the fleet

Provenance

Source conceptSourceVersion
BGC0001117MIBIG5
CHEBI:190009CHEBI3-star

This page is generated from data/natural_products/amino_acids_and_peptides/himastatin.yaml, which is generated from the committed inventories. Neither is edited by hand.