NaturalProductMech

itaconic acid

CHEBI:30838 EXACT SEEDED cytotoxic

A dicarboxylic acid that is methacrylic acid in which one of the methyl hydrogens is substituted by a carboxylic acid group.

Structure

Standard InChIKeyLVHBHZANLOWSRM-UHFFFAOYSA-N
SMILESC=C(CC(=O)O)C(=O)O
Stereochemistryfully defined
Cross-referencespubchem:811

Filing pathway

Fatty acids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is other, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Ustilago maydis
NCBITaxon:5270
SOURCE_ASSERTION mibig:BGC0001286 DOI:10.1038/s41598-021-97352-x

Occurrences 18

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Pycnandra acuminata
NCBITaxon:280718
LOTUS DOI:10.1016/J.PHYTOCHEM.2007.07.001
Arabidopsis thaliana
NCBITaxon:3702
LOTUS DOI:10.1073/PNAS.0609709104
Arabidopsis thaliana
NCBITaxon:3702
LOTUS DOI:10.1111/PCE.12714
Phaseolus vulgaris
NCBITaxon:3885
LOTUS DOI:10.3390/METABO4030599
Vicia faba
NCBITaxon:3906
LOTUS DOI:10.1002/ELPS.201300646
Vicia faba
NCBITaxon:3906
LOTUS DOI:10.1007/BF00381261
Vicia faba
NCBITaxon:3906
LOTUS DOI:10.1016/J.PLAPHY.2015.04.008
Vicia faba
NCBITaxon:3906
LOTUS DOI:10.1104/PP.69.2.522
Solanum tuberosum
NCBITaxon:4113
LOTUS DOI:10.1016/J.PHYTOCHEM.2016.12.003
Lilium longiflorum
NCBITaxon:4690
LOTUS DOI:10.1016/0031-9422(81)83095-6
Caenorhabditis elegans
NCBITaxon:6239
LOTUS DOI:10.3389/FMOLB.2018.00096
Ustilago cynodontis
NCBITaxon:63396
LOTUS DOI:10.1080/00021369.1990.10870333
Ustilago cynodontis
NCBITaxon:63396
LOTUS DOI:10.1080/00021369.1990.10870334
Ustilago cynodontis
NCBITaxon:63396
LOTUS DOI:10.1271/BBB1961.54.2359
Homo sapiens
NCBITaxon:9606
LOTUS DOI:10.1007/S11306-016-1051-4
Homo sapiens
NCBITaxon:9606
LOTUS DOI:10.1038/NBT.2488
Homo sapiens
NCBITaxon:9606
CHEBI PMID:23610393
Ustilago maydis
NCBITaxon:5270
LOTUS DOI:10.1111/1751-7915.12329

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0001286 Ustilago maydis
NCBITaxon:5270
CLUSTER_UNSTATED genbank:KT852988.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Bioactivities 22

AssayResultReference
Adrenergic beta2 receptor (ADRB2) small molecule agonists, cell-based qHTS assay: Summary1.90226 uMpubchem.aid:2061107
Adrenergic beta2 receptor (ADRB2) small molecule agonists, cell-based qHTS assay: Summary1.90226 uMpubchem.aid:2061107
Caspase-3/7 induction in HepG2 cells by small molecules, qHTS cell viability counter screen28.4485 uMpubchem.aid:1346981
Cytochrome P450 Family 1 Subfamily A Member 2 (CYP1A2) small molecule antagonists: luciferase reporter qHTS assay81.2025 uMpubchem.aid:1671199
Cytochrome P450 Family 1 Subfamily A Member 2 (CYP1A2) small molecule antagonists: luciferase reporter qHTS assay81.2025 uMpubchem.aid:1671199
Cytochrome P450 Family 1 Subfamily A Member 2 (CYP1A2) small molecule antagonists: luciferase reporter qHTS assay74.0014 uMpubchem.aid:1671199
Cytochrome P450 Family 1 Subfamily A Member 2 (CYP1A2) small molecule antagonists: luciferase reporter qHTS assay74.0014 uMpubchem.aid:1671199
Cytochrome P450 Family 2 Subfamily C Member 19 (CYP2C19) small molecule antagonists: luciferase reporter qHTS assay40.6977 uMpubchem.aid:1671197
Cytochrome P450 Family 2 Subfamily C Member 19 (CYP2C19) small molecule antagonists: luciferase reporter qHTS assay40.6977 uMpubchem.aid:1671197
Cytochrome P450 Family 2 Subfamily C Member 9 (CYP2C9) small molecule antagonists: luciferase reporter qHTS assay72.3718 uMpubchem.aid:1671198
Cytochrome P450 Family 2 Subfamily C Member 9 (CYP2C9) small molecule antagonists: luciferase reporter qHTS assay72.3718 uMpubchem.aid:1671198
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes52.3416 uMpubchem.aid:1963577
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes47.6849 uMpubchem.aid:1963577
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes: Summary44.0399 uMpubchem.aid:1963585
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes: Summary44.0399 uMpubchem.aid:1963585
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes: Summary47.6849 uMpubchem.aid:1963585
p53 small molecule agonists, cell-based qHTS assay with human liver microsomes: Summary47.6849 uMpubchem.aid:1963585
qHTS assay for identifying genotoxic compounds that show differential cytotoxicity against isogenic chicken DT40 cell lines with known DNA damage response pathways - Rev3 mutant cell line78.4482 uMpubchem.aid:743014
qHTS assay to identify small molecule agonists of the farnesoid-X-receptor (FXR) signaling pathway - cell viability counter screen7.2071 uMpubchem.aid:743218
qHTS assay to identify small molecule antagonists of the androgen receptor (AR) signaling pathway using the MDA cell line13.9503 uMpubchem.aid:743042
qHTS assay to identify small molecule antagonists of the estrogen receptor alpha (ER-alpha) signaling pathway - cell viability counter screen11.1771 uMpubchem.aid:743074
qHTS assay to identify small molecule antagonists of the peroxisome proliferator-activated receptor delta (PPARd) signaling pathway56.0183 uMpubchem.aid:743215

Provenance

Source conceptSourceVersion
BGC0001286MIBIG3
CHEBI:30838CHEBI3-star

This page is generated from data/natural_products/fatty_acids/itaconic-acid.yaml, which is generated from the committed inventories. Neither is edited by hand.