NaturalProductMech

sporothriolide

CHEBI:141338 EXACT SEEDED antifungal

A furofuran that is (3aR,6aR)-hexahydrofuro[3,4-b]furan substituted by an oxo group at positions 2 and 4, methylene group at position 3 and by an hexyl group at position 6. It is a metabolite isolated from several species of fungi.

Structure

Standard InChIKeyAENZSPQGLJVLND-VWYCJHECSA-N
SMILESCCCCCC[C@@H]1[C@H]2[C@H](C(=C)C(=O)O2)C(=O)O1
Stereochemistryfully defined
Cross-referencesnpatlas:NPA017246, pubchem:10944473

Filing pathway

Polyketides — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is pks, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Hypomontagnella monticulosa
NCBITaxon:2487000
SOURCE_ASSERTION mibig:BGC0002262 PMID:34123230

Occurrences 5

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Nodulisporium sp. A21
NCBITaxon:1647372
CHEBI PMID:27017876
Sporothrix sp.
NCBITaxon:1902615
CHEBI PMID:8119853
Sporothrix
NCBITaxon:29907
LOTUS DOI:10.7164/ANTIBIOTICS.47.113
Hypomontagnella monticulosa
NCBITaxon:2487000
LOTUS DOI:10.1021/ACS.JNATPROD.7B00714
Hypoxylon monticulosum
NCBITaxon:2487000
CHEBI PMID:29043802

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0002262 Hypomontagnella monticulosa
NCBITaxon:2487000
CLUSTER_UNSTATED genbank:MT889334.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Elsewhere in the fleet

Provenance

Source conceptSourceVersion
BGC0002262MIBIG2
CHEBI:141338CHEBI3-star

This page is generated from data/natural_products/polyketides/sporothriolide.yaml, which is generated from the committed inventories. Neither is edited by hand.