NaturalProductMech

o-orsellinic acid

CHEBI:32807 EXACT SEEDED enzyme inhibitor

A dihydroxybenzoic acid that is 2,4-dihydroxybenzoic acid in which the hydrogen at position 6 is replaced by a methyl group.

Structure

Standard InChIKeyAMKYESDOVDKZKV-UHFFFAOYSA-N
SMILESCC1=CC(=CC(=C1C(=O)O)O)O
Stereochemistryfully defined
Cross-referencespubchem:68072, npatlas:NPA024876, chembl:CHEMBL457583

Filing pathway

Shikimates and phenylpropanoids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is pks, terpene, from MIBiG.

Producer organisms 5

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Aspergillus nidulans FGSC A4
NCBITaxon:227321
BGC_CHARACTERIZED mibig:BGC0000057 PMID:20174687
Fusarium graminearum PH-1
NCBITaxon:229533
BGC_CHARACTERIZED mibig:BGC0002594 PMID:25011010
Colletotrichum higginsianum IMI 349063
NCBITaxon:759273
BGC_CORRELATED mibig:BGC0002812 DOI:10.1016/j.ymben.2023.10.002
Moniliophthora roreri MCA 2997
NCBITaxon:1381753
SOURCE_ASSERTION mibig:BGC0002212 DOI:10.1126/sciadv.aar5459
Claviceps purpurea 20.1
NCBITaxon:1111077
SOURCE_ASSERTION mibig:BGC0002596 PMID:33130255

Occurrences 22

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Nidularia pulvinata
NCBITaxon:1081941
LOTUS DOI:10.1515/ZNC-1997-5-606
Hypoxylon rubiginosum
NCBITaxon:110542
LOTUS DOI:10.1021/NP040063L
Penicillium purpurogenum
NCBITaxon:1266744
CHEBI PMID:21879714
Ascomycota sp. Ind19F07
NCBITaxon:1583058
CHEBI PMID:25537370
Aspergillus nidulans
NCBITaxon:162425
LOTUS DOI:10.1073/PNAS.0901870106
Parmotrema stuppeum
NCBITaxon:2041279
LOTUS DOI:10.1515/ZNC-2000-11-1227
Parmotrema tinctorum
NCBITaxon:235862
LOTUS DOI:10.4268/CJCMM20141620
Dolichousnea longissima
NCBITaxon:281306
LOTUS DOI:10.1016/S0031-9422(00)82466-8
Parmotrema cooperi
NCBITaxon:2910500
LOTUS DOI:10.1007/S11426-011-4436-2
Aspergillus terreus
NCBITaxon:33178
LOTUS DOI:10.1016/J.PHYTOL.2015.02.009
Aspergillus terreus
NCBITaxon:33178
LOTUS DOI:10.1039/C39720000391
Penicillium aurantiogriseum
NCBITaxon:36655
LOTUS DOI:10.1039/C39920000646
Chaetomium globosum
NCBITaxon:38033
LOTUS DOI:10.1021/NP058014B
Umbilicaria torrefacta
NCBITaxon:392743
LOTUS DOI:10.1016/0031-9422(90)83052-3
Aspergillus flavus
NCBITaxon:5059
LOTUS DOI:10.1271/BBB.63.820
Penicillium
NCBITaxon:5073
LOTUS DOI:10.1021/NP500885F
Escherichia coli
NCBITaxon:562
LOTUS DOI:10.1073/PNAS.0901870106
Penicillium cyclopium
NCBITaxon:60167
LOTUS DOI:10.1039/C39920000646
Aspergillus fumigatus
NCBITaxon:746128
LOTUS DOI:10.1042/BJ0970321
Aspergillus fumigatus
NCBITaxon:746128
LOTUS DOI:10.1042/BJ0980353
Aspergillus fumigatus
NCBITaxon:746128
LOTUS DOI:10.1080/13693780802307720
Stachybotrys cylindrospora
NCBITaxon:80386
LOTUS DOI:10.1139/V93-069

Biosynthetic gene clusters 5

AccessionHostLocus evidenceGenome
mibig:BGC0000057 Aspergillus nidulans FGSC A4
NCBITaxon:227321
CLUSTER_DEMONSTRATED genbank:AACD01000135.1
mibig:BGC0002594 Fusarium graminearum PH-1
NCBITaxon:229533
CLUSTER_DEMONSTRATED genbank:CM000575.1
mibig:BGC0002812 Colletotrichum higginsianum IMI 349063
NCBITaxon:759273
CLUSTER_CORRELATED genbank:LTAN01000004.1
mibig:BGC0002212 Moniliophthora roreri MCA 2997
NCBITaxon:1381753
CLUSTER_UNSTATED genbank:AWSO01000045.1
mibig:BGC0002596 Claviceps purpurea 20.1
NCBITaxon:1111077
CLUSTER_UNSTATED genbank:CAGA01000059.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Bioactivities 5

AssayResultReference
Validation qHTS for agonist of cAMP-regulated guanine nucleotide exchange factor 3 (EPAC1)89.1251 uMpubchem.aid:1645883
Validation qHTS for agonist of cAMP-regulated guanine nucleotide exchange factor 3 (EPAC1)89.1251 uMpubchem.aid:1645883
qHTS Assay for Activators of Cytochrome P450 3A425.1189 uMpubchem.aid:885
qHTS Assay for Inhibitors and Substrates of Cytochrome P450 3A425.1189 uMpubchem.aid:884
qHTS Assay for Inhibitors of the Human Apurinic/apyrimidinic Endonuclease 1 (APE1)0.0089 uMpubchem.aid:2517

Open questions 2

name-disagreement — ChEBI calls this structure 'o-orsellinic acid' and MIBiG calls it 'Orsellinic acid', 'orsellinic acid'. They share a Standard InChIKey, so if the names denote different compounds then one upstream record has the wrong structure. Check which.

shared-structure — This structure is reported by more than one MIBiG entry: BGC0000057, BGC0002212, BGC0002594, BGC0002596, BGC0002812. Confirm they describe the same compound rather than an upstream cross-reference error.

Provenance

Source conceptSourceVersion
BGC0000057MIBIG5
BGC0002594MIBIG2
BGC0002812MIBIG2
BGC0002212MIBIG3
BGC0002596MIBIG2
CHEBI:32807CHEBI3-star

This page is generated from data/natural_products/shikimates_and_phenylpropanoids/o-orsellinic-acid.yaml, which is generated from the committed inventories. Neither is edited by hand.