NaturalProductMech

avermitilol

CHEBI:63702 EXACT SEEDED

A carbotricyclic compound that consists of decahydro-1H-1H-cyclopropa[a]naphthalene bearing four methyl substituents at position 1, 1, 3a and 7 as well as a hydroxy substituent at position 4 (the (1aR,3aS,4S,7R,7aS,7bR)-diastereomer).

Structure

Standard InChIKeyBLGPPSRDEKNCLT-CDWXYHGHSA-N
SMILES[H][C@@]12CC[C@]3(C)[C@@H](O)CC[C@@H](C)[C@@]3([H])[C@]1([H])C2(C)C
Stereochemistryfully defined
Cross-referencesnpatlas:NPA019411

Filing pathway

Terpenoids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is terpene, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Streptomyces avermitilis MA-4680 = NBRC 14893
NCBITaxon:227882
SOURCE_ASSERTION mibig:BGC0000683 PMID:20536237

Occurrences 1

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Streptomyces avermitilis
NCBITaxon:33903
LOTUS DOI:10.1021/JA103087W

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0000683 Streptomyces avermitilis MA-4680 = NBRC 14893
NCBITaxon:227882
CLUSTER_UNSTATED genbank:BA000030.3

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Provenance

Source conceptSourceVersion
BGC0000683MIBIG3
CHEBI:63702CHEBI3-star

This page is generated from data/natural_products/terpenoids/avermitilol.yaml, which is generated from the committed inventories. Neither is edited by hand.