NaturalProductMech

(−)-δ-cadinene

CHEBI:63703 EXACT SEEDED

A member of the cadinene family of sesquiterpenes in which the double bonds are located at the 4-4a and 7-8 positions, and in which the isopropyl group at position 1 is cis to the hydrogen at the adjacent bridgehead carbon (the 1R,8aS-enantiomer).

Structure

Standard InChIKeyFUCYIEXQVQJBKY-UKRRQHHQSA-N
SMILESCC1=C[C@@H]2[C@H](CCC(=C2CC1)C)C(C)C
Stereochemistryfully defined
Cross-referencespubchem:12306055

Filing pathway

Terpenoids — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is terpene, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Streptomyces clavuligerus ATCC 27064
NCBITaxon:1901
SOURCE_ASSERTION mibig:BGC0000674 PMID:21276937

Occurrences 3

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Marchantia quadrata
NCBITaxon:2729092
LOTUS DOI:10.1016/0031-9422(96)00354-8
Gossypium hirsutum
NCBITaxon:3635
LOTUS DOI:10.1021/JF60200A011
Streptomyces clavuligerus
NCBITaxon:1901
LOTUS DOI:10.1016/J.CHEMBIOL.2010.11.008

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0000674 Streptomyces clavuligerus ATCC 27064
NCBITaxon:1901
CLUSTER_UNSTATED genbank:DS570637.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Provenance

Source conceptSourceVersion
BGC0000674MIBIG5
CHEBI:63703CHEBI3-star

This page is generated from data/natural_products/terpenoids/cadinene.yaml, which is generated from the committed inventories. Neither is edited by hand.