NaturalProductMech

pirazofurin

CHEBI:90284 EXACT SEEDED antimicrobial unspecified

A C-glycosyl compound that is 4-hydroxy-1H-pyrazole-5-carboxamide in which the hydrogen at position 3 has been replaced by a β-D-ribofuranosyl group.

Structure

Standard InChIKeyXESARGFCSKSFID-FLLFQEBCSA-N
SMILESNC(=O)C1=C(O)C([C@@H]2O[C@H](CO)[C@@H](O)[C@H]2O)=N[NH]1
Stereochemistryfully defined
Cross-referencesnpatlas:NPA033439, pubchem:135413551, chembl:CHEMBL2105330

Filing pathway

Unclassified — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is other, from MIBiG.

Producer organisms 1

A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.

TaxonBasisClusterEvidence
Streptomyces candidus
NCBITaxon:67283
SOURCE_ASSERTION mibig:BGC0001985 DOI:10.1002/anie.201910356

Occurrences 2

Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.

TaxonSourceReference
Streptomyces sparsogenes
NCBITaxon:67365
LOTUS DOI:10.1016/S0021-9673(01)83861-9
Streptomyces candidus
NCBITaxon:67283
LOTUS DOI:10.1128/AAC.5.1.90

Biosynthetic gene clusters 1

AccessionHostLocus evidenceGenome
mibig:BGC0001985 Streptomyces candidus
NCBITaxon:67283
CLUSTER_DEMONSTRATED genbank:MN305320.1

A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.

Elsewhere in the fleet

Open questions 1

name-disagreement — ChEBI calls this structure 'pirazofurin' and MIBiG calls it 'Pyrazofurin'. They share a Standard InChIKey, so if the names denote different compounds then one upstream record has the wrong structure. Check which.

Provenance

Source conceptSourceVersion
BGC0001985MIBIG4
CHEBI:90284CHEBI3-star

This page is generated from data/natural_products/unclassified/pirazofurin.yaml, which is generated from the committed inventories. Neither is edited by hand.