waikikiamide C
naturalproductmech:mibig-689f97d555 MINTED SEEDED
Structure
| Standard InChIKey | GKOOPMJBANLQKC-DXXYEOPISA-N |
|---|---|
| SMILES | CO[C@H]1C2=C(N(O)C3=C2C=CC2=C3[C@@H](OC)[C@H](ON3C(=O)[C@@]4(C[C@@]56NC(=O)[C@]7(CCCN7C5=O)C[C@H]6C4(C)C)C4=C3C3=C(C=C4)OC(C)(C)C=C3)C(C)(C)O2)C(C)(C)[C@@H]2C[C@]34CCCN3C(=O)[C@]12NC4=O |
| Stereochemistry | fully defined |
| Cross-references | npatlas:NPA032308 |
Filing pathway
Unclassified — computed by NPClassifier npclassifier.gnps2.org@2026-09-07, which is why it is pinned rather than recomputed. The gene cluster's asserted class is pks, from MIBiG.
Producer organisms 2
A claim that this taxon makes the compound. The basis says what the evidence addressed — a knockout and a database assertion are not the same claim.
| Taxon | Basis | Cluster | Evidence |
|---|---|---|---|
| Aspergillus sp. FM242 NCBITaxon:2741095 |
SOURCE_ASSERTION | mibig:BGC0002253 | PMID:32433885 |
| Aspergillus sp. FM242 NCBITaxon:2741095 |
SOURCE_ASSERTION | mibig:BGC0002254 | PMID:32433885 |
Occurrences 1
Somebody found the compound in this organism and cited it. That is not a claim that the organism makes it, and nothing here promotes one to the other.
| Taxon | Source | Reference |
|---|---|---|
| Aspergillus NCBITaxon:5052 |
LOTUS | DOI:10.1021/ACS.ORGLETT.0C01411 |
Biosynthetic gene clusters 2
| Accession | Host | Locus evidence | Genome |
|---|---|---|---|
| mibig:BGC0002253 | Aspergillus sp. FM242 NCBITaxon:2741095 |
CLUSTER_UNSTATED | genbank:MT457560.1 |
| mibig:BGC0002254 | Aspergillus sp. FM242 NCBITaxon:2741095 |
CLUSTER_UNSTATED | genbank:MT457561.1 |
A locus claim and a taxon claim are different questions. Heterologous expression settles the first and leaves the second where the isolation report left it.
Open questions 1
shared-structure — This structure is reported by more than one MIBiG entry: BGC0002253, BGC0002254. Confirm they describe the same compound rather than an upstream cross-reference error.
Provenance
| Source concept | Source | Version |
|---|---|---|
| BGC0002253 | MIBIG | 3 |
| BGC0002254 | MIBIG | 3 |
This page is generated from data/natural_products/unclassified/waikikiamide-c.yaml, which is generated from the committed inventories. Neither is edited by hand.